The xanthate route to all-carbon quaternary centers

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2019,（11）
• 页码范围: 1450-1462
• 页数: 13页
• 语种: 英文

摘要

This review discusses the numerous routes to all-carbon quaternary centers based on the unique radical chemistry of xanthates.It summarizes the various approaches to the synthesis of tertiary xanthates then describes the intra-and intermolecular radical additions and combinations thereof that have so far been used to construct quaternary centers.