PhIO-mediated Synthesis of Ketones from Alkynes and Alkenes

• 来源期刊: 高等学校化学研究（英文版）
• 年，卷（期）: 2019,（1）
• 页码范围: 26-32
• 页数: 7页
• 语种: 英文
• DOI: 10.1007/s40242-019-8264-9

摘要

A facile and efficient method for the preparation of methyl ketones was developed in the reaction of alkynes and alkenes with PhIO-BFyEt2O.The reaction features mild conditions,short time and metal-free catalyst.The possible mechanism for the formation of methyl ketones was proposed.H2O functions as both a nucleophile and an oxygen source.