Iodine(Ⅲ) reagent (ABX-N3)-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes

• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2019,（11）
• 页码范围: 1537-1541
• 页数: 5页
• 语种: 英文

摘要

Anti-Markovnikov hydroazidation of unactivated alkenes using ABX-N3 as an initiator has been developed at room temperature,wherein hydrogen azide (HN3) acts as both hydrogen and azidating agent.Notably,the HN3 reagent was generated from azidotrimethylsilane (TMSN3) and acetic acid in situ.The reaction itself displays broad substrate scope,good yields and excellent regioselectivities.