A novel 58-nuclei silver nanowheel encapsulating a subvalent Ag64+ kernel
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摘要:
The combination of CrO42-anion and N,N'-dimethylformamide (DMF)-containing solvent helps to stabilize an atom-precise ultrasmall Ag6 kernel into a 52-nuclei silver shell,giving a core-shell Ag6@Ag52 wheel-like structure (SD/Ag58b).The solution behavior and photocurrent response property were investigated in details.