New family of single-component Ni catalysts for ethylene polymerization to high and ultrahigh molecular weight polyethylene

• 作者: Artem A.Antonov Konstantin P.Bryliakov Wen-Hua Sun
• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2020,（6）
• 页码范围: 753-754
• 页数: 2页
• 语种: 英文

摘要

Since the milestone discovery of Ni(Ⅱ) salicylaldiminate catalysts by Grubbs and co-workers [1], nickel(Ⅱ) complexes with N,N-and N,O-donor ligands have strengthened their lead in the search for highly active platforms for olefins homo-and copolymerization with various co-monomers, including those with polar groups, to achieve polymers with precisely controlled microstructures [2,3].The most attractive and fruitful features of such catalysts have been their simplicity and exceptional synthetic flexibility of the ligand frameworks, as well as high and versatile catalytic reactivity [4,5].