A review of enantioselective dual transition metal/photoredox catalysis

• 作者: Chengjian Zhu Hong-Hao Zhang Hui Chen Shouyun Yu
• 来源期刊: 中国科学:化学（英文版）
• 年，卷（期）: 2020,（5）
• 页码范围: 637-647
• 页数: 11页
• 语种: 英文

摘要

Transition metal catalysis is one of the most important tools to construct carbon-carbon and carbon-heteroatom bonds in modern organic synthesis.Visible-light photoredox catalysis has recently drawn considerable attention of the scientific community owing to its unique activation modes and significance for the green synthesis.The merger ofphotoredox catalysis with transition metal catalysts,termed metallaphotoredox catalysis,has become a popular strategy for expanding the synthetic utility of visiblelight photocatalysis.This strategy has led to the discovery of novel asymmetric transformations,which are unfeasible or not easily accessible by a single catalytic system.This contemporary area of organic chemistry holds promise for the development of economical and environmentally friendly methods for the asymmetric synthesis of ehiral compounds.In this review,the advances in the enantioselective metallaphotoredox catalysis (EMPC) are summarized.