La2Zr2O7 and MgO co-doped composite Li-Garnet solid electrolyte
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摘要:
Various solid electrolytes,such as sulfides (10-3-10-2 S cm-1)and oxides (10-4-10-3 S cm-1) are explored and developed to solve the safety problems in commercial Li-ion batteries using liquid flammable electrolytes.Metallic Li anode is required for pursuing high power density (>300Wh kg-1) for solid-state batteries [1,2].However,sulfide electrolytes react with Li and the products are ionic/electronic insulators Li3P and Li2S [3-6].