Synthesis and Characterization of a Metal-Organic Framework Bridged by Long Flexible Ligand

• 作者: Kawther Osman Ashiry Rasha Khalid Abbas
• 来源期刊: 高分子化学期刊(英文)
• 学科: 化学
• 关键词: Coordination Polymer Hydrogen Bond Metal-Organic Frameworks LIGAND
• 年，卷（期）: 2021,（1）
• 页码范围: 1-9
• 页数: 9页
• 分类号: O62

摘要

3D supramolecular network with considerable volume pores was created via hydrogen bond & C-H</span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">--</span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">π. By </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">tightening </span></span></span><span><span><span style="font-family:""><span style="font-family:Verdana;">of The metal-organic frameworks (MOF) namely [Ni(μ-pmb)</span>_{<span style="font-family:Verdana;">2</span>}<span style="font-family:Verdana;">(H</span>_{<span style="font-family:Verdana;">2</span>}<span style="font-family:Verdana;">O)</span>_{<span style="font-family:Verdana;">2</span>}<span style="font-family:Verdana;">]</span>_{<span style="font-family:Verdana;">n</span>}<span style="font-family:Verdana;"> (pmb = 3,5-bis(4-pyridylmethylenoxyl)</span></span></span></span><span><span><span style="font-family:""> </span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">benzoate, that have been synthesized by hydrothermal method. Complex 1 crystallizes in triclinic P-1 space group and consists of 1D semi zigzag chain.