Self-assembly of 3p-Block Metal-based Metal-Organic Frameworks from Structural Perspective

• 作者: QIAO Junyi LIU Xinyao ZHANG Lirong LIU Yunling
• 来源期刊: 高等学校化学研究（英文版）
• 年，卷（期）: 2022,（1）
• 所属期刊栏目: Reviews
• 页码范围: 31-44
• 页数: 14页
• 语种: 英文

摘要

Metal-organic frameworks(MOFs) are a class of porous inorganic-organic hybrid materials,which are constructed from diverse inorganic building units and multi-functional organic ligands.Highly ordered pore structures and tailored functionalization have made MOF materials potential for applications in many fields.Among various MOF materials,3p-block metal(Al,Ga,and In)-based MOFs exhibit higher chemical stability than divalent transition metal-based MOFs due to their higher valence.In this review,Al-MOFs and In-MOFs were mainly discussed from the perspective of categories of inorganic building blocks,coordination types,and numbers of organic ligands.This review will give intuitive guidance to the design and synthesis of novel 3p-block metal-based MOFs with potential applications.