【正】 The positron annihilation lifetime and Doppler broadened line-shapeparameter have been measured between 77 and 300 K for Bi<sub>1.8</sub>Pb<sub>0.1</sub>Sb<sub>0.1</sub>Sr<sub>2</sub>Ca<sub>2</sub>Cu<sub>3</sub>O<sub>x</sub>,Bi<sub>1.8</sub>Sb<sub>0.2</sub>Sr<sub>2</sub>Ca<sub>2</sub>Cu<sub>3</sub>O<sub>x</sub> and Bi<sub>1.7</sub>Pb<sub>0.2</sub>Sb<sub>0.1</sub>Sr<sub>2</sub>Ca<sub>2</sub>Cu<sub>2</sub>O<sub>x</sub>. The charge transfer from Cu-Olayers to Bi-O layers has been observed across T<sub>c</sub>s for all samples.Three samples allshow two normal state anomalies around 160 K and 240 K,respectively.The anomalyaround 160 K is attributed to the structural instability and that around 240 Kpresumably to the displacement phase transition.