Formulation of the System of Isohydric Solutions

• 作者: Agustin G. Asuero Tadeusz Micha?owski
• 来源期刊: 分析科学方法和仪器期刊(英文)
• 学科: 数学
• 关键词: Isohydric SOLUTIONS PH TITRATION
• 年，卷（期）: 2012,（1）
• 页码范围: 1-4
• 页数: 4页
• 分类号: O1

摘要

The isohydricity (pH constancy) as the property referred to mixtures of acids or bases, is illustrated on a simple example of the solutions: HL (C0, mol/L) and HL (C mol/L) mixed according to titrimetric mode (pH titration). A new derivation of the Michalowski formula C0=C+C2·10PK1 expressing this property is presented, and its applicability for determination of pK1 = – logK1 value is indicated. The principle of the isohydric method of pK1 determination is also outlined.