Compact Formulation of Redox Systems According to GATES/GEB Principles

• 作者: Anna Maria Micha?owska-Kaczmarczyk Tadeusz Micha?owski
• 来源期刊: 分析科学方法和仪器期刊(英文)
• 学科: 数学
• 关键词: Electrolytic Redox Systems GENERALIZED Electron BALANCE
• 年，卷（期）: fxkxffhyqqkyw,（2）
• 页码范围: 39-45
• 页数: 7页
• 分类号: O1

摘要

The Generalized Electron Balance (GEB), together with charge balance and concentration balances, completes the set of equations needed for resolution of electrolytic redox systems. The general formulae for GEB were obtained according to Approach II to GEB, i.e., on the basis of the equation 2?f(O) ? f(H) obtained from elemental balances: f(H) for H, and f(O) for O. Equivalency of the Approach II and the Approach I to GEB was proved for an aqueous solution and a binary-solvent system. On this basis, a compact form of GEB was derived.