Design and prediction for highly efficient SO2 capture from flue gas by imidazolium ionic liquids

• 作者: Lili Jiang Ke Mei Kaihong Chen Rina Dao Haoran Li Congmin Wang
• 来源期刊: 绿色能源与环境（英文版）
• 年，卷（期）: 2022,（1）
• 所属期刊栏目: Research papers
• 页码范围: 130-136
• 页数: 7页
• 语种: 英文

摘要

An efficient method for prediction in the capture of SO2 from flue gas by imidazolium ionic liquids was reported, where the concentration of SO2 is 2000 ppm. On the basis of quantitative calculations through a combination of Langmuir simulation, theoretical calculation and quantum chemical method, SO2 absorption and desorption performance from flue gas by twelve kinds of imidazolium ionic liquids with different anions were designed and predicted. Then, among them, five kinds of imidazolium ionic liquids were chosen and prepared to investigate their behavior of SO2 absorption capacity, desorption residue, and available absorption capacity. The results indicated that the experimental values were in good agreement with the predicted values. Thus, an ideal ionic liquid [Emim][Tetz] was obtained through the predictive method for the capture of SO2 of 2000 ppm, which showed high available absorption capacity of 0.24 g SO2 per g ionic liquid and excellent reversibility.