The increasing demands of multifunctional organic electronics require advanced organic semiconducting materials to be developed and significant improvements to be made to device performance.Thus,it is necessary to gain an in-depth un-derstanding of the film growth process,electronic states,and dynamic structure-property relationship under realistic opera-tion conditions,which can be obtained by in-situ/operando characterization techniques for organic devices.Here,the up-to-date developments in the in-situ/operando optical,scanning probe microscopy,and spectroscopy techniques that are em-ployed for studies of film morphological evolution,crystal structures,semiconductor-electrolyte interface properties,and charge carrier dynamics are described and summarized.These advanced technologies leverage the traditional static characteriza-tions into an in-situ and interactive manipulation of organic semiconducting films and devices without sacrificing the resolu-tion,which facilitates the exploration of the intrinsic structure-property relationship of organic materials and the optimization of organic devices for advanced applications.