Star nonfullerene acceptors like ITIC[1],IDIC[2],O-IDTBR[3],IT-4F[4],CO,8DFIC[5],Y6[6]etc.continuously emerge and keep pushing the power conversion efficiency(PCE)of organic sol-ar cells forward.These small molecules generally show nar-row bandgaps,excellent visible to NIR light-harvesting capabil-ity,good electron mobility,suitable energy levels and miscibil-ity with the donor materials.PCEs up to 18.56%have been achieved for the state-of-the-art nonfullerene organic solar cells[7].On the other hand,donor materials matching non-fullerene acceptors also received considerable interests[8].Ow-ing to complementary light absorption,high hole-mobility and deep HOMO levels,wide-bandgap(WBG)conjugated co-polymers are ideal donor partners for the low-bandgap non-fullerene acceptors.